The Effect of Thallium (I) Salts on The Electrochemical Properties of Gold

In recent years, extensive research is being carried out concerning oxide layers on noble metal surfaces because of their importance in fuel-cells. In this study the effect of the small amounts of thallium acetate and thallium nitrate on the electrochemical properties of gold has been investigated. For this purpose, using cyclic volt-metric method current-potential curves were obtained. The electrode used in this work was a gold wire, reference and counter electrodes were calomel and platinum electrodes. Before each experiment electrode was oxidized and then reduced in 1N H2SO4 and reference curve was obtained in this medium. In the same concentration of thallium acetate and thallium nitrate, the anodic current observed in a medium with acetate was smaller than that observed with nitrate.